Autor/es reacciones

Arjan W. Kleij

Group leader at the Institute of Chemical Research of Catalonia (ICIQ) & ICREA Fellow

This work is in my view an excellent example of an inter-disciplinary and comprehensive synthetic and mechanistic approach to create new life for consumer plastics by developing a catalytic degradation of PET waste. In particular, the use of advanced spectroscopic analysis (CEST-NMR) allowed the researchers to gather information on reaction intermediates while optimizing the conversion of PET through selective semi-hydrogenation into an important base chemical: 4-(hydroxymethyl)benzoate (EHMB) that previously was not accessible through similar initiatives. EHMB can be upcycled into a variety of agrochemicals and pharmaceuticals, and a new type of recyclable polyester, hence serving several potential markets.

Furthermore, while this work is mostly explorative in nature, the advantageous process conditions, high catalytic efficiency and scalability clearly add to its economic potential. A life-cycle analysis (LCA) further demonstrates that the EHMB produced from PET waste compares favorably to fossil-fuel derived EHMB in terms of its environmental impact. It therefore creates new incentives for circular materials and molecules in the area, and offers a seminal example of a joint approach to plastic recycling.

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